In the client it's not an option, so I didn't even try specifying the Storage Format.
The following command works!:
New-HardDisk -VM $vm -Datastore $datastore -CapacityGB (1.99 * 1024) -StorageFormat Thin
Thanks, Luc!
Edit: By not an option, I mean it's grayed out:
![2014-04-08 12-34-37_Add Hardware.jpg]()